By Helene Pellissier
Content material: Ch. 1. Chiral auxiliaries -- Ch. 2. Chiral catalysts -- Ch. three. Enzymatic tools -- Ch. four. Use of transition metals and enzymes in tandem -- Ch. five. Atroposelective reactions
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Additional info for Chirality from dynamic kinetic resolution
5 equiv) 2. 61 ( )n ( )m N H Ph DKR using aza-Cope rearrangements. 9 Conclusions In the last ﬁfteen years, a wide number of various chiral auxiliaries have been employed in DKR processes occurring in diﬀerent types of reactions. One of the most studied reactions has been the nucleophilic substitution on conﬁgurationally labile alkyl halides, involving compounds with a bromo or iodo atom in the a-position with respect to a carboxylic acid derivative, in which the Chiral Auxiliaries 45 SN2 reaction is governed by a chiral auxiliary placed in the carboxylic moiety.
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