By Leibniz Gottfried Wilhelm
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Extra info for A Unitary Principle of Optics, Catoptrics, and Dioptrics
Dipole moments may also be induced in the crystal via interaction of the incident photon with more than one phonon, although with reduced oscillator strength; this is the origin of lattice absorption in pure diamond. From a classical viewpoint, the absorption mechanism can be qualitatively understood as one phonon inducing a net charge on atoms, and a second phonon (or more) vibrating the induced charge to create a dipole moment . 2 Two-, three-, and four-phonon lattice absorption bands. The underlying figure showing the calculated (smooth solid curve) and measured absorption spectra is reprinted with permission from Ref.
The chapter focuses on the optical properties spanning from ultraviolet (UV) to infrared (IR). It should be noted that, throughout the chapter, Système Internationale (SI) units have been used, apart from some exceptions to stay with conventions. The data provided refer to diamond with the naturally occurring isotopic ratio, unless specifically stated otherwise. 1 Transmission Diamond has a wide bandgap and lacks first-order infrared absorption, which makes it one of the most broadly transmitting of all solids.
KGaA. Published 2013 by Wiley-VCH Verlag GmbH & Co. KGaA. 2 1 Intrinsic Optical Properties of Diamond also includes the dependence of optical properties on basic variables such as wavelength, temperature, and isotopic composition. Although the scope is limited to bulk intrinsic properties, the intention is to stimulate a further expansion of the knowledge base as the limits of measurement resolution and performance are extended, and as more detailed investigations emerge into areas such as surface optics, crystal variants, and nano-optical effects.